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Surface Area Effect on the Rate of a Chemical Reaction - Dust Explosions

Video Links

The following links contain a video demonstration of dust explosions and combustion. Videos are available in both avi and quicktime file formats.
Dust Explosion (1.1 MB, quicktime, 58 sec)
Dust Explosion (1.6 MB, microsoft avi, 16 sec)
Dust Combustion (1.3 MB, microsoft avi, 9 sec)

Materials and Construction

The materials required for the demonstration are shown below in two still images.

(34 kb jpg)  The first shows the components unassembled,
(32 kb jpg) and the second shows the components assembled for the demonstration, before the cover is placed over the large coffee can.

The fuel, in this case commercial cornstarch, is placed into a small container. After this container is placed inside the large coffee can, the small container is connected to an external tube through the side wall of the coffee can. A burning candle is placed inside the coffee can and the can is sealed. When the cornstrach is dispersed as a finely divided powder by blowing through the tube, the dust is ignited by the candle. The pressure buildup caused by the rapid accumulation of the gaseous combustion products causes the lid of the coffee can to be blown off.


Chemical Process

The balanced overall combustion reaction, assuming complete combustion, can be represented as

(C6H10O5)n + 6n O2 --> 6n CO2 + 5n H2O.

The explosive effect results from the increase in pressure due to confinement of the rapidly produced gaseous combustion products; notice the 11n moles of gaseous products compared with only 6n moles of gaseous reactants. The same reaction can be made to occur, albeit much more slowly, when a small pile of cornstarch is placed on the table and ignited with a match or butane lighter. The significant increase in the reaction rate when the fuel is dispersed as a fine powder occurs because the increase in the exposed surface area of the fine dust particles allows more of the fuel to interact with the oxidizer (in this case air).


Video Details

The video files for this demonstration were created by filming the process with a standard VHS video camera and transfering the video to a PC using a Pinnacle Systems DC30 video capture card. The video files were then created using Adobe Premire 5.1 to edit the clip and create the quicktime and avi files.


The authors would like to thank the staff of the Faculty Media Center at Widener University for their assistance in the preparation of this demonstration.

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